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Acrylic can be heated to make it pliable. It will become rigid again when it cools. Never heat acrylic in a kitchen oven. Explosive fumes can accumulate inside the oven, and ignite.
A strip heater is the best tool to form acrylic. This tool will only form straight line bends. Buy one from your acrylic dealer. The strip heater will heat just the area to be formed.
Heat the sheet until it begins to sag at the bend line. The bend should be made away from the side exposed to the heating element. Sheet thicker than 3/16" should be heated on both sides for a proper bend. Use forming jigs or clamps for best results, and wear heavy cotton gloves when handling heated acrylic.
Forming other than straight line bends will generally require specialized equipment and jigs